46.Nucleophilic Fluoroalkylation of α,β-Enones, Arynes and Activated Alkynes with Fluorinated Sulfones: Probing the Hard/Soft Nature of Fluorinated Carbanions

Ni, Chuanfa; Zhang, Laijun; Hu, Jinbo* (N.C. and Z.L. contributed equally) J. Org. Chem. 2008, 73, 5699-5713.
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45.Electrophilic (Phenylsulfonyl)difluoro-methylation of Thiols with a Hypervalent Iodine(III)-CF2SO2Ph Reagent

Zhang, Wei; Zhu, Jieming; Hu, Jinbo* Tetrahedron Lett. 2008, 49, 5006-5008.
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44.Enantioselective Nucleophilic Difluoromethylation of Aromatic Aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H Reagents Catalyzed by Chiral Quanternary Ammonium Salts

Ni, Chuanfa; Wang, Fang; Hu, Jinbo* Beilstein J. Org. Chem. 2008, 4, No.21.
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43.Fluoride Ion-Mediated Nucleophilic Fluoroalkylation of Alkyl Halides with Me3SiCF2SPh

Li, Ya; Hu, Jinbo* J. Fluorine Chem. 2008, 129, 382-385.
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42.Stereoselective Synthesis of α-Difluoromethyl-β-Amino Alcohols via Nucleophilic Difluoromethylation of α-Dibenzylamino Aldehydes with Me3SiCF2SO2Ph

Liu, Jun; Ni, Chuanfa; Wang, Fang; Hu, Jinbo* Tetrahedron Lett. 2008, 49, 1605-1608.
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41.Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group

Mogi, Ryo; Morisaki, Kazuo; Hu, Jinbo; Prakash, G. K. Surya*; Olah, George A. Journal of Fluorine Chemistry, 2007, 128, 1098-1103.
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40.Selective Fluoroalkylations with Fluorinated Sulfones, Sulfoxides, and Sulfides

Prakash, G. K. Surya*; Hu, Jinbo Accounts of Chemical Research 2007, 40, 921 - 930.
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39.Chlorodifluoromethyl Phenyl Sulfone: A Novel Non-ODS-Based Difluorocarbene Reagent for O- and N-Difluoromethylations

Zheng, Ji; Li, Ya; Zhang, Laijun; Hu, Jinbo*, Meuzelaar, Gerrit Joost; Federsel, Hans-Jurgem Chem. Comm. 2007, 5149-5151.
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38.Electrophilic Monofluoromethylation of O-, S-, N-Nucleophiles with Chlorofluoromethane

Zhang, Wei; Zhu, Lingui; Hu, Jinbo* Tetrahedron, 2007, 63, 10569-10575.
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37.Radical (Phenylsulfonyl)difluoromethylation with Iododifluoromethyl Phenyl Sulfone

Li, Ya; Liu, Jun; Zhang, Laijun; Zhu, Lingui; Hu, Jinbo* J. Org. Chem. 2007, 72, 5824-5827.
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36.Nucleophilic (Phenylsulfinyl)difluoromethylation of Carbonyl Compounds with Difluoromethyl Phenyl Sulfoxide

Zhu, Lingui; Li, Ya; Ni, Chuanfa; Hu, Jinbo*; Beier, Petr; Wang, Ying; Prakash, G. K. Surya*; Olah, George, A. J. Fluorine Chem. 2007, 128, 1241-1247.
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35.Preparation of 1-Aryl-2,2-Difluoro Enol Esters via Dehydrosulfonylation of α-(Phenyldulfonyl)difluoromethylated Benzoates

Zhang, Laijun; Li, Ya; Hu, Jinbo* J. Fluorine Chem. 2007, 128, 755-761.
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34.Stereoselective Synthesis of Di- and Monofluoromethylated Vicinal Ethylenediamines with Di- and Monofluoromethyl Sulfones

Liu, Jun; Li, Ya; Hu, Jinbo* J. Org. Chem. 2007, 72, 3119-3121.
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33.Stereoselective Difluoromethylenation Using TMSCF2SPh: Synthesis of Chiral 3,3-Difluoro-2,4-Disubstituted Pyrrolidines

Li, Ya; Hu, Jinbo* Angew. Chem. Int. Ed. 2007, 46, 2489–2492.
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32.A Remarkably Efficient Fluoroalkylation of Cyclic Sulfates and Sulfamidates: Facile Entry into β-Difluoromethylated or β-Difluoromethylenated Alcohols and Amines

Ni, Chuanfa; Liu, Jun; Zhang, Laijun; Hu, Jinbo* Angew. Chem. Int. Ed. 2007, 46, 786–789.
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